Sulfur nanocomposites with insecticidal effect for the control of Bactericera cockerelli

• Lany S. Araujo-Yépez,
• Juan O. Tigrero-Salas,
• Vicente A. Delgado-Rodríguez,
• Vladimir A. Aguirre-Yela and
• Josué N. Villota-Méndez

Beilstein J. Nanotechnol. 2023, 14, 1106–1115, doi:10.3762/bjnano.14.91

• processes that involve classical nucleation, aggregation, and/or Ostwald ripening [38]. Figure 6 shows a STEM micrograph of the nanomicellar structure of a rosemary NCMP composed of two immiscible phases, that is, (a) the aqueous phase formed by the sulfur nanoparticles and (b) the oily phase formed by

• particles and an oily phase made up of eucalyptus or rosemary essential oils with concentrations of 0.25%, 0.5%, and 0.75%. The increase in size of the nanocomposites is related to agglomeration and effects such as Ostwald ripening, or the increase in essential oil concentration. In addition, the

Control of morphology and crystallinity of CNTs in flame synthesis with one-dimensional reaction zone

• Muhammad Hilmi Ibrahim,
• Norikhwan Hamzah,
• Mohd Zamri Mohd Yusop,
• Ni Luh Wulan Septiani and
• Mohd Fairus Mohd Yasin

Beilstein J. Nanotechnol. 2023, 14, 741–750, doi:10.3762/bjnano.14.61

• temperatures and lower HAB values, the particles can combine, sinter, and increase in size either due to Ostwald ripening or particle migration and coalescence [26]. The agglomeration occurs because of the high temperature, creating conditions similar to annealing. At higher HAB values, where the temperature

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

Polymer nanoparticles from low-energy nanoemulsions for biomedical applications

• Santiago Grijalvo and
• Carlos Rodriguez-Abreu

Beilstein J. Nanotechnol. 2023, 14, 339–350, doi:10.3762/bjnano.14.29

• component addition or on the thermal history. Nanoemulsions are not to be confused with microemulsions, which are equilibrium systems with thermodynamic stability [4]. Because of their very small drop size, the main mechanism for nanoemulsion destabilization is commonly attributed to Ostwald ripening

• Ostwald ripening, especially considering that the solubility of ethyl acetate in water is relatively high (about 80 g/L at 20 °C). The hydrodynamic diameter of the particles decreases sharply (from 300–400 nm to ca. 40 nm) at a given electrolyte concentration (Figure 4b), with a concomitant decrease in

Biocatalytic synthesis and ordered self-assembly of silica nanoparticles via a silica-binding peptide

• Mustafa Gungormus

Beilstein J. Nanotechnol. 2023, 14, 280–290, doi:10.3762/bjnano.14.25

• coalescence and Ostwald ripening of the particles. Growth by coalescence and Ostwald ripening is a fundamental process that plays a dominant role in nanoparticle formation. In coalescence, two or more particles combine to form a larger particle, whereas in Ostwald ripening, small particles dissolve in a

• condensation polymerization of the hydrolyzed precursor. Once colloidally stable nuclei form, growth ensues through monomer addition or coalescence and Ostwald ripening. The reactions involved in the Stöber process are described as follows: where Equation 2 is the ionization of the ammonia, Equation 3 is the

Sputtering onto liquids: a critical review

• Anastasiya Sergievskaya,
• Adrien Chauvin and
• Stephanos Konstantinidis

Beilstein J. Nanotechnol. 2022, 13, 10–53, doi:10.3762/bjnano.13.2

• reversible agglomeration, irreversible aggregation, or Ostwald ripening (Figure 7) [77][79][80][83][110]. When agglomerates or aggregates form a precipitate in colloidal solution, the process is called coagulation. The fact that such secondary processes take place in a colloidal solution of primary metal NPs

Revealing the formation mechanism and band gap tuning of Sb₂S₃ nanoparticles

• Maximilian Joschko,
• Franck Yvan Fotue Wafo,
• Christina Malsi,
• Danilo Kisić,
• Ivana Validžić and
• Christina Graf

Beilstein J. Nanotechnol. 2021, 12, 1021–1033, doi:10.3762/bjnano.12.76

• process and formed superordinate structures (type III). This process was followed by the crystallization of these particles and a layer-like growth of the crystalline particles by an Ostwald ripening process at the expense of the amorphous particles. It was demonstrated that the kinetic control of the

• ). These particles were 2.6 ± 0.9 µm in length with an aspect ratio between 4 and 5 and resembled the type III structures. Still, there were mainly particles of the prior stage remaining. The crystalline rods grew apparently at the expense of the spherical, amorphous nanoparticles in an Ostwald ripening

• distribution of the spherical, amorphous particles in the samples obtained after 12 and 16 h, respectively. A decreasing diameter with progressing reaction time is visible and likely due to Ostwald ripening. The size distribution curves were calculated assuming a Gaussian distribution. Nanoparticles obtained

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

• Nabojit Das,
• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2021, 12, 924–938, doi:10.3762/bjnano.12.69

• of DESs facilitates rapid nucleation yielding tiny particles that undergo Ostwald ripening through a slow process, allowing for the manipulation on the nanoscale with controlled crystal growth. Plasmonic metal nanoparticle synthesis using DESs Plasmonic metal nanoparticles, such as gold, silver, and

Comprehensive review on ultrasound-responsive theranostic nanomaterials: mechanisms, structures and medical applications

• Sepand Tehrani Fateh,
• Lida Moradi,
• Elmira Kohan,
• Michael R. Hamblin and
• Amin Shiralizadeh Dezfuli

Beilstein J. Nanotechnol. 2021, 12, 808–862, doi:10.3762/bjnano.12.64

Characterization, bio-uptake and toxicity of polymer-coated silver nanoparticles and their interaction with human peripheral blood mononuclear cells

• Sahar Pourhoseini,
• Reilly T. Enos,
• Angela E. Murphy,
• Bo Cai and
• Jamie R. Lead

Beilstein J. Nanotechnol. 2021, 12, 282–294, doi:10.3762/bjnano.12.23

• of NPs are related to Ostwald ripening of NPs [36], as evidenced in our STEM results. The subsequent reduction in size is explained as further transformations that are dominated by dissolution [36]. UV–vis spectroscopy data suggest some aggregation and possible shape changes after reprecipitation at

A review on the green and sustainable synthesis of silver nanoparticles and one-dimensional silver nanostructures

• Sina Kaabipour and
• Shohreh Hemmati

Beilstein J. Nanotechnol. 2021, 12, 102–136, doi:10.3762/bjnano.12.9

One-step synthesis of carbon-supported electrocatalysts

• Sebastian Tigges,
• Nicolas Wöhrl,
• Ivan Radev,
• Ulrich Hagemann,
• Markus Heidelmann,
• Thai Binh Nguyen,
• Stanislav Gorelkov,
• Stephan Schulz and
• Axel Lorke

Beilstein J. Nanotechnol. 2020, 11, 1419–1431, doi:10.3762/bjnano.11.126

• electrochemical long-term stability of these electrodes is often unsatisfactory due to particle coalescence and Ostwald ripening [15]. These degradation processes can be avoided by increasing interparticle distance (at the expense of the electrochemically active surface) or by creating barriers to prevent NP

Analysis of catalyst surface wetting: the early stage of epitaxial germanium nanowire growth

• Owen C. Ernst,
• Felix Lange,
• David Uebel,
• Thomas Teubner and
• Torsten Boeck

Beilstein J. Nanotechnol. 2020, 11, 1371–1380, doi:10.3762/bjnano.11.121

• system due to material re-evaporation and Ostwald ripening describes the theoretically predicted and experimentally obtained results. Thus, dewetting phenomena of thin metal layers can be used to manufacture nanostructured devices. From this point of view, the application of gold droplets as catalysts to

• grow germanium nanowires on different substrates is described. Keywords: dewetting; germanium; interfacial energy; Laplace pressure; nanostructure; nanowire; Ostwald ripening; wetting layer; Introduction Wetting phenomena as well as the formation and movement of droplets are essential for numerous

• droplets are characterized by a high surface curvature, which leads to a high Laplace pressure. As the temperature rises, the Laplace pressure in the droplets increases, increasing the likelihood of re-evaporation as long as the pressure is not reduced by other effects, such as Ostwald ripening. Ostwald

Microfluidics as tool to prepare size-tunable PLGA nanoparticles with high curcumin encapsulation for efficient mucus penetration

• Nashrawan Lababidi,
• Valentin Sigal,
• Aljoscha Koenneke,
• Konrad Schwarzkopf,
• Andreas Manz and
• Marc Schneider

Beilstein J. Nanotechnol. 2019, 10, 2280–2293, doi:10.3762/bjnano.10.220

• organic phase volume accordingly. At a flow rate ratio of 0.05, a substantial reduction of the NP size from ≈150 to 70 nm was obtained (Figure 1). The reduction in the NP size is attributed to the rapid and efficient mixing process as described in literature [36]. Further, the Ostwald ripening phenomena

Preservation of rutin nanosuspensions without the use of preservatives

• Pascal L. Stahr and
• Cornelia M. Keck

Beilstein J. Nanotechnol. 2019, 10, 1902–1913, doi:10.3762/bjnano.10.185

• ., polydispersity indices (PdI values) above 0.3 and some larger particles with sizes above 4 µm (Table 1). Because of this, the nanosuspensions were expected to be prone to Ostwald ripening, i.e., particle growth during storage was expected. Limited physical stability of suspensions is advantageous if a study aims

• this are the more pronounced particle growth due to Ostwald ripening at elevated temperatures and/or destabilization due to accelerated bacterial growth, which might excrete compounds that contribute to changes in pH value or conductivity in the medium or interact with the particles. Such changes

• should become visible in the zeta potential values. However, this was not the case in this study (Figure 8). Therefore, the observed destabilization at elevated temperatures of the non-preserved nanosuspensions might be more related to Ostwald ripening. The assumption is also underlined by the fact that

Highly ordered mesoporous silica film nanocomposites containing gold nanoparticles for the catalytic reduction of 4-nitrophenol

• Mohamad Azani Jalani,
• Leny Yuliati,
• Siew Ling Lee and
• Hendrik O. Lintang

Beilstein J. Nanotechnol. 2019, 10, 1368–1379, doi:10.3762/bjnano.10.135

• nanochannels, suggesting a weak interaction between AuNPs with the porous silica structure and the possibility of Ostwald ripening during both heat treatments. Another reason for such an observation could be due to the use of TEM with higher electron energy during the measurement. Moreover, the presence of

Deposition of metal particles onto semiconductor nanorods using an ionic liquid

• Michael D. Ballentine,
• Elizabeth G. Embry,
• Marco A. Garcia and
• Lawrence J. Hill

Beilstein J. Nanotechnol. 2019, 10, 718–724, doi:10.3762/bjnano.10.71

• ][15][16][17]. The low surface tension of ionic liquids causes high nucleation rates and allows for the synthesis of small nanoparticles with minimal Ostwald ripening [17]. Further, many ionic liquids consist of a large anion with diffuse negative charge; this lack of strongly binding anionic ligands

Ultrasonication-assisted synthesis of CsPbBr₃ and Cs₄PbBr₆ perovskite nanocrystals and their reversible transformation

• Longshi Rao,
• Xinrui Ding,
• Xuewei Du,
• Guanwei Liang,
• Yong Tang,
• Kairui Tang and
• Jin Z. Zhang

Beilstein J. Nanotechnol. 2019, 10, 666–676, doi:10.3762/bjnano.10.66

• transformation into Cs4PbBr6 PNCs. This process is related to Ostwald ripening that was found during the nucleation and growth of PNCs [42]. Therefore, the formation of Cs4PbBr6 PNCs is promoted by the capacity of the organic ligands to dissolve PbBr2 and by the dissociation of CsPbBr3 PNCs. A series of TEM

Gold nanoparticles embedded in a polymer as a 3D-printable dichroic nanocomposite material

• Lars Kool,
• Anton Bunschoten,
• Aldrik H. Velders and
• Vittorio Saggiomo

Beilstein J. Nanotechnol. 2019, 10, 442–447, doi:10.3762/bjnano.10.43

• reflection. The explanation is that, while boiling, the gold nanowires fragment, creating nanoparticles with a large head and a slim and long tail, comparable to a tadpole. Over time the tail starts to shrink, due to intra-particle Ostwald ripening to minimize the total surface energy of the nanoparticle

A Ni(OH)₂ nanopetals network for high-performance supercapacitors synthesized by immersing Ni nanofoam in water

• Donghui Zheng,
• Man Li,
• Yongyan Li,
• Chunling Qin,
• Yichao Wang and
• Zhifeng Wang

Beilstein J. Nanotechnol. 2019, 10, 281–293, doi:10.3762/bjnano.10.27

• ] directions [37]. The anisotropic growth leads to the formation of high-density crosslinked nanopetals. The flower-like structures composed of Ni(OH)2 nanopetals are formed through Ostwald ripening [38]. Meanwhile, the dissolved tiny and unstable plates provide the source material for the growth of plates

Mechanism of silica–lysozyme composite formation unravelled by in situ fast SAXS

• Tomasz M. Stawski,
• Daniela B. van den Heuvel,
• Rogier Besselink,
• Dominique J. Tobler and
• Liane G. Benning

Beilstein J. Nanotechnol. 2019, 10, 182–197, doi:10.3762/bjnano.10.17

• that the observed change is caused by a partial coalescence or Ostwald ripening of NPs inside of the aggregates. It is well documented that silica NPs synthesized from monosilicic acid are internally highly disordered and hydrated at their surfaces [31]. Previous studies found that the initially formed

Site-controlled formation of single Si nanocrystals in a buried SiO₂ matrix using ion beam mixing

• Xiaomo Xu,
• Thomas Prüfer,
• Daniel Wolf,
• Hans-Jürgen Engelmann,
• Lothar Bischoff,
• René Hübner,
• Karl-Heinz Heinig,
• Wolfhard Möller,
• Stefan Facsko,
• Johannes von Borany and
• Gregor Hlawacek

Beilstein J. Nanotechnol. 2018, 9, 2883–2892, doi:10.3762/bjnano.9.267

• , kMC simulations can be used to follow the thermally induced phase separation and formation of a single chain of individual Si NCs. Snapshots from the simulation of this process are presented in Figure 5b–d. As one can see, Ostwald ripening leads to a reduction of the NC number with increasing number

Oriented zinc oxide nanorods: A novel saturable absorber for lasers in the near-infrared

• Pavel Loiko,
• Tanujjal Bora,
• Josep Maria Serres,
• Haohai Yu,
• Magdalena Aguiló,
• Francesc Díaz,
• Uwe Griebner,
• Valentin Petrov,
• Xavier Mateos and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2018, 9, 2730–2740, doi:10.3762/bjnano.9.255

• perpendicular to the glass substrate. In the initial growth periods, Ostwald ripening competes with the growth and results in merging of thinner NRs with thicker ones. With time, this process saturates and the growth continues. This is the reason why the growth of the NRs is not linear at the early stage of the

Droplet-based synthesis of homogeneous magnetic iron oxide nanoparticles

• Christian D. Ahrberg,
• Ji Wook Choi and
• Bong Geun Chung

Beilstein J. Nanotechnol. 2018, 9, 2413–2420, doi:10.3762/bjnano.9.226

• nucleation and growth predicts a narrowing of the particle size distribution with increasing reaction time [35][36], the opposite is observed in our experiments. This is probably due to classical models not including effects such as Ostwald ripening and, in our case more significant, the aggregation of

Fabrication and photoactivity of ionic liquid–TiO₂ structures for efficient visible-light-induced photocatalytic decomposition of organic pollutants in aqueous phase

• Anna Gołąbiewska,
• Marta Paszkiewicz-Gawron,
• Aleksandra Sadzińska,
• Wojciech Lisowski,
• Ewelina Grabowska,
• Adriana Zaleska-Medynska and
• Justyna Łuczak

Beilstein J. Nanotechnol. 2018, 9, 580–590, doi:10.3762/bjnano.9.54

• a combination of electrostatic and steric stabilization. 1-Methyl-3-octadecylimidazolium chloride is probably less firmly packed on the TiO2 surface due to the longer alkyl chain. As a result, the [ODMIM][Cl] ionic liquid may limit smaller particle deposition during Ostwald ripening, thus inhibiting